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United Initiators NOROX?AZOX FRED Acetylacetone peroxide 37187-22-7

NOROX ? AZOX FRED is a red solution of acetylacetone peroxide (AAP) or 2,4-pentanedione peroxide with stabilizers.NOROX ? AZOX is a very effective polymerization initiator for the room temperature cure of unsaturated polyester resins, and can be worked in most resin systems at very fast cure times with little or no effect on gel time. This performance characteristic is particularly beneficial in resin transfer molding (RTM), cast polymers, and other applications where rapid mold turnaround is required to increase productivity.An additional benefit of NOROX ? AZOX FRED is the low fire or explosion hazard. In the U.S., a precautionary organic peroxide yellow label is not required for shipping.

It is worth noting that the red dye added to this material will help indicate the progress of curing when mixed, as the color fades indicating that curing is in progress.

Technical data

  • Active oxygen: 4.4
  • Form: Liquid
  • Color: Red
  • Specific gravity (25°C): 1.15
  • Viscosity: 16.0 cps
  • Flash Point (C.O.C.): 200°F/93°C, min.
  • Flash Point (SETA C.C.): 150°F/66°C, min.
  • Soluble in: water, ethers, ketones and alcohols
  • Insoluble in: aromatics, chlorinated hydrocarbons and aliphatic hydrocarbons

appliance NOROX ? AZOX FRED is an extremely effective initiator for fast curing in many resin systems without significantly shortening the gel time.NOROX ? AZOX FRED is best suited for cobalt-only promoted resins using 0.1% to 0.5% cobalt (naphthenic or octanoic acid in 6% solution). In some cases, the addition of 0.1% to 0.3% of diethyl or dimethylaniline accelerates the resin cure, producing an extremely high exothermic cure. The type and level of resin inhibitor also has a significant effect on the performance of NOROX ? AZOX FRED. In general, high inhibitor levels are usually undesirable, and some quaternary ammonium salts can cause significant yellowing of the resin, as well as inhibit the gel and cure characteristics of the resin system.

NOROX ? AZOX FRED curing initiators have observed excellent final cure and dimensional stability in toolmaking and RTM applications.

APPLICATION RESULTS Tables I and II show the results that can be obtained using NOROX ? AZOX FRED compared to standard MEKP formulations.

Table I - Gel and Cure Data for Marble Resins Table II - Gel and Cure Data for Composite Resins

In addition, NOROX ? AZOX FRED is often used in combination with standard MEKP formulations, and the specific mixing ratio will give intermediate results between the two products, depending on the mixing ratio. Tables III and IV compare the gel and cure characteristics of several AAP/MEKP blends in casting and laminating resins.

Packaging, transportation and supply

  • NOROX ? AZOX FRED is available in standard package sizes of 4x8 lb and 44 lb (20 kg) polyethylene bottles.
  • NOROX ? AZOX FRED that can be pre-colored in 44 lb (20 kg) bottles. see United Initiators, Inc. technical data sheet on peroxide dye concentrates.
  • Classification - Refer to sections 14 and 15 of the specific NOROX ? AZOX FRED Safety Data Sheet (SDS) for transportation and regulatory information.

PLEASE NOTE: NOROX ? AZOX FRED is available through a global network. contact United Initiators, Inc. for the name of the distributor in your area.

statement denying or limiting responsibility The information provided and all further technical recommendations - whether verbal, written or experimental - are based on our existing knowledge of in-house testing of local raw materials. They are intended to inform interested parties about our products and their possible applications. They should not be interpreted as a guarantee of the performance of a particular product or its suitability for a particular application. Furthermore, this information does not contain complete instructions for use. Nor does it constitute a guarantee of quality and durability. Changes are reserved due to technological advances and company developments. Any existing third-party copyrights should be taken into account.

Applications and uses of our products based on our application-specific recommendations are beyond our control and are solely the responsibility of the user. The user is not relieved of the obligation to verify the suitability and applicability of the purchased goods for the intended purpose.

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We have rich experience in exporting hazardous chemicals, covering Class 5.2 (including products for cold chain transportation), Class 3 and Class 9 dangerous goods. Our services have been extended to more than 40 countries worldwide, including the Middle East, Central Asia and Eastern Europe.

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